info@aliah.ac.in        

Department of  CHEMISTRY



Dr. Md. Hedayetullah Mir Assistant Professor / CHEMISTRY

Email : chmmir@gmail.com

Address : Department of Chemistry, Aliah University, IIA/27 New Town, Kolkata- 700 156

Phone : Phone: +913323416504

Room No : Faculty Room, 3rd Floor, Left Block

Joined : November 2010

Education

Post Doc (2010 Jul-Oct)ERATO KITAGAWA Integrated Pores Project, Japan Science and Technology (JST)

                       Research Advisor: Prof. Susumu Kitagawa (predicted  nominee for 2010 Nobel Prize in Chemistry by Thomson Reuters)

PhD (2010) :   National University of Singapore, Singapore

                        Research Advisor: Prof. J. J. Vittal

M.Sc. (2006) : IIT Madras, India

                        Research Advisor: Prof. D. K. Chand

B. Sc. (2004) : University of Calcutta, India

Teaching Experience

Department of Chemsitry, Aliah University

Since November 2010 till date

Field of Specialization

Inorganic Chemistry

Supramolecular Chemistry

Courses Taught/Teaching

Autumn Semester

CH 101 : General Chemistry- I

CH 131 : Subsidiary Chemitsry- I

CH 401 : Advanced Inorganic Chemsitry

CH 191 : Chemistry Lab- I

CH 491 : Advanced Chemistry Lab- I

Spring Semester

CH 104 : Inorganic Chemistry- I

CH 302 : Inorganic Chemsitry- III

CH 516 : Organic Synthesis-II (Supramolecular Chemistry)

CH 162 : General Chemistry Lab

CH 292 : Chemistry Lab- III

Research Area

Inorganic Materials and Supramolecular Chemistry

  • Metal-organic frameworks (MOFs)/Coordination polymers (CPs) 
  • Applications in gas storage, conductivity, Schottky diodes, sensing etc.
  • Solid-state structural transformations
  • Photoreactive coordination polymers
  • Water clusters in crystal hosts

Experience

Post Doctoral Fellow: ERATO KITAGAWA Integrated Pores Project, Japan Science and Technology (JST), Kyoto Research Park, Japan (July 2010 - November 2010)

Research Advisor: Prof. Susumu Kitagawa (predicted nominee for 2010 Nobel Prize in Chemistry by Thomson Reuters)

Journal Papers Published

 

  1. B. Dutta, C. Sinha and M. H. Mir* "Sunlight-driven photosalient effect of 1D coordination polymer and release of an elusive cyclobutane derivative" Chem. Commun. 2019 DOI: 10.1039/C9CC06016B.

  2. B. Dutta, K. Pal, K. Jana, C. Sinha and M. H. Mir* "Synthesis and Antimicrobial Activity of a Zn(II)-Based 2D Pillar Bilayer Metal-Organic Framework" ChemistrySelect 2019 (In Press)

  3. A. zaman, S. Khan, B. Dutta, S. M. Yakout, S. S. Ibrahim and M. H. Mir* " Synthesis and characterization of a new 4-Styrylpyridine based square planar copper(II) complex: Exploration of phenoxazinone synthase mimicking activity" J. Coord. Chem. 2019, DOI: 10.1080/00958972.2019.1651297.

  4. B. Dutta, C. Sinha,  and M. H. Mir* "Supramolecular assembly of Cu(II)-based 1D coordination polymer: Synthesis, characterization and correlation of band gap" J. Mol. Struct.  2019, 1197, 430-435.

  5. B. Dutta, A. Dey, C. Sinha, P. P. Ray* and M. H. Mir* "Tuning of para- position of pyridyl ligands impacts the electrical properties of a series of Cd(II) ladder polymers" Dalton Trans. 2019, 48, 11259–11267.

  6. S. Islam, J. Datta, S. Maity, B. Dutta, S. Khan, P. Ghosh, P. P. Ray* and M. H. Mir* "Photodimerization of 1D Ladder Polymer Through Single-Crystal to Single-Crystal Transformation has Effect on Electrical Conductivity" Cryst. Growth Des. 2019, 19, 4057-4062 (Invited Article for "Virtual Special Issue" on "Structure Property relationship in Crystalline Solids").

  7. B. Dutta, A. Dey, C. Sinha, P. P. Ray* and M. H. Mir* "Sunlight Induced Topochemical Photodimerization and Switching of the Conductivity of a Metal-Organic Compound" Inorg. Chem. 2019, 58, 5419−5422.

  8. B. Dutta, D. Das, J. Datta, A. Chandra, S. Jana, C. Sinha, P. P. Ray* and M. H. Mir*, "Synthesis of a Zn(II)-based 1D zigzag coordination polymer for the fabrication of optoelectronic device with remarkably high photosensitivity" Inorg. Chem. Front. 20196, 1245–1252.

  9. S. Islam, J. Datta, S. Maity, B. Dutta, F. Ahmed, P. Ghosh, P. P. Ray* and M. H. Mir* “Halogen•••π Interactions in Supramolecular Architecture of 1D Coordination Polymers and Their Electrical Conductance” ChemistrySelect 2019, 4, 3294–3299.

  10. B. Dutta, S. Maity, S. Ghosh, C. Sinha and M. H. Mir* “Acetylenedicarboxylato bridged Mn(II)-based 1D coordination polymer: electrochemical CO2 reduction and magnetic properties” New J. Chem. 2019, 43, 5167-5172.

  11. B. Dutta, R. Jana, A. K. Bhanja, P. P. Ray*, C. Sinha* and M. H. Mir* "Supramolecular Aggregate of Cadmium (II)-Based one-Dimensional Coordination Polymer for Device Fabrication and Sensor Application" Inorg. Chem. 201958, 2686-2694.

  12. F. Ahmed, S. R. Ghosh, S. Halder, S. Guin, S. M. Alam, P. P. Ray*, A. D. Jana* and M. H. Mir* "Metal-ligand ring aromaticity in a 2D coordination polymer used as a photosensitive electronic devic" New J. Chem. 201943, 2710-2717.

  13. B. Dutta, C. Sinha and M. H. Mir* "Synthesis and crystal structure of a CdII-based 2D coordination polymer and determination of band gap" J. Indian Chem. Soc. 2018, 95, 1535-1540. (Invited Article, Special Issue, ICS Convention)

  14. B. Dutta, A. Dey, S. Maity, C. Sinha, P. P. Ray* and M. H. Mir* "Supramolecular Assembly of a Zn(II)-Based 1D Coordination Polymer through Hydrogen Bonding and pi...pi Interactions: Crystal Structure and Device Applications" ACS Omega 2018, 3, 12060-12067 (Invited Article).

  15. B. Dutta, J. Datta, S. Maity, C. Sinha, D. Sun, P. P. Ray* and M. H. Mir* "Electrical property and Schottky behavior of a flexible Schiff-base compound: X-ray structure and stabilization of 1D water chainPhys. Chem. Chem. Phys. 201820, 24744-24749.

  16. S. Islam, J. Datta, F. Ahmed, B. Dutta, S. Naaz, P. P. Ray* and M. H. Mir* "Effect on Schottky behavior of 1D coordination polymers by altering para-substituent on the benzoate ligand" New J. Chem. 2018, 42, 13971-13977.

  17. B. Dutta, A. Dey, C. Sinha, P. P. Ray* and M. H. Mir* "Photochemical Structural Transformation of a Linear 1D Coordination Polymer Impacts the Electrical Conductivity" Inorg. Chem. 201857, 8029-803.

  18. B. Dutta, R. Jana, C. Sinha, P. P. Ray* and M. H. Mir* "Synthesis of Cd(II) based 1D coordination polymer by in situ ligand generation and fabrication of photosensitive electronic device" Inorg. Chem. Front. 2018, 2018, 5, 1998–2005 (Hot Paper).

  19. F. Ahmed, J. Datta, B. Dutta, S. Sarkar, A. D. Jana,* P. P. Ray* and M. H. Mir* "Water Tetramer Confinement and Photosensitive Schottky Behavior of a 2D Coordination Polymer" ChemistrySelect 20183, 6985–6991.

  20. B. Dutta, A. Dey, K. Naskar,  S. Maity, F. Ahmed, S. Islam, C. Sinha, P. Ghosh, P. P. Ray* and M. H. Mir"Two isostructural linear coordination polymers: Size of metal ion impacts the electrical conductivity" New J. Chem. 2018, 42, 1030910316.

  21. B. Dutta, S. M. Pratik, S. Jana, C. Sinha, A. Datta* and M. H. Mir*, "Novel Br···π(Chelate) interaction in a 1D coordination polymer revealing aromaticity" ChemistrySelect 20183, 4289– 4291.

  22. B. Dutta, A. Dey, K. Naskar,  F. Ahmed, R. Purkait, S. Islam, S. Ghosh, C. Sinha, P. P. Ray* and M. H. Mir* "Cu(II)-based binuclear compound for the application of photosensitive electronic device" New J. Chem. 2018, 42, 8629--8637.

  23. F. Ahmed, S. Halder, B. Dutta, S. Islam, C. Sen, S. kundu, C. Sinha, P. P. Ray* and M. H. Mir* "Synthesis and structural characterization of Cu(II)-based 1D coordination polymer and its application in Schottky device" New J. Chem. 2017, 41, 11317-11323.

  24. K.Naskar, A. Dey, B. Dutta, F. Ahmed, C. Sen, M. H. Mir, P. P. Roy, and C. Sinha "Intercatenated coordination polymers (ICPs) of carboxylato bridged Zn(II)-isoniazid and their electrical conductivity" Cryst. Growth Des. 2017, 17, 3267–3276

  25. F. Ahmed, J. Datta, B. Dutta, K. Naskar, C. Sinha, S. M. Alam, S. kundu, P. P. Ray* and M. H. Mir* "Cation dependent charge transport in linear dicarboxylate based isotypical 1D coordination polymers" RSC Adv20177, 10369–10375.

  26. F. Ahmed, S. Roy, K. Naskar, C. Sinha, S. M. Alam, S. kundu, J. J. Vittal* and M. H. Mir* "Halogen···halogen interactions in the supramolecular assembly of 2D coordination polymers and the CO2 sorption behavior” Cryst. Growth Des201616, 5514-5519.

  27. M. H. Mir and J. J. Vittal, “Muconate bridged coordination polymers of Cu(II): Effect of auxiliary ligand on their structural architectures” Inorg. Chim. Acta 2013403, 97-101.

  28. R. A. Laskar, N. A. Begum, M. H. Mir, M. R. Rohman and A. T. Khan, “Nickel(II) chloride hexahydrate catalyzed reaction of aromatic aldehydes with 2-mercaptoethanol: Formation of supramolecular helical assemblage of the product” Tetrahedron lett2013, 54, 5839-5844.

  29.  A. T. Khan, A. Ghosh, R. S. Basha, and M. H. Mir, “Synthesis of trisubstituted 1H-pyrazole-4-carbodithioate using one-pot three-component reaction catalyzed by ferric sulfate [Fe2(SO4)3·xH2O]” Asian J. Org. Chem20132,126-129.

  30. R. A. Laskar, N. A. Begum, M. H. Mir, S. Ali and A. T. Khan, “Hydrogen-bond-driven stereoselective syntheses of b-enaminoesters and b-enaminones by vanadium(IV) acetylacetonate catalyzed reaction” Tetrahedron lett201354, 436-440.

  31. A. T. Khan, R. S. Basha, M. Lal and M. H. Mir, “Formation of unexpected α-amino amidine through three-  component UGI condensation reaction,” RSC Adv. 20122, 5506–5509.

  32. H. Sato, R. Matsuda, M. H. Mir and S. Kitagawa, “Photochemical cycloaddition on the pore surface of a porous coordination polymer impacts on the sorption behavior,” Chem. Commun201248, 7919-7921.

  33. M. H. Mir, J. X. Ong, G. K. Kole, G. K. Tan, M. J. McGlinchey, Y. Wu and J. J. Vittal, “Photoreactive gold(I) macrocycles with diphosphine andtrans, trans- muconate Ligands,” Chem. Commun2011, 47, 11633-11635.

  34. M. H. Mir, G. K. Tan, L. L. Koh and J. J. Vittal, “Single-crystal to single-crystal photochemical structural transformations of interpenetrated 3D coordination polymers by [2+2] cycloaddition reactions,” Angew. Chem. Int. Ed201049, 390–393.

  35. M. H. Mir, L. Wang, M. W. Wong and J. J. Vittal, “Water helicate, (H2O)7 hosted by diamondoid metal-organic framework,” Chem. Commun.2009, 4539–4541.

  36. M. H. Mir, S. Kitagawa and J. J. Vittal, “Two- and three-fold interpenetrated metal-organic frameworks from one-pot crystallization,” Inorg. Chem200847, 7728–7733.

  37. M. H. Mir and J. J. Vittal, “Single-crystal to single-crystal transformation of cyclic water heptamer to another (H2O)7 cluster containing cyclic pentamer,” Cryst. Growth Des20088, 1478–1480.

  38. M. H. Mir and J. J. Vittal, “Phase transition accompanied by transformation of elusive discrete cyclic water heptamer to bicyclic (H2O)7 cluster,” Angew. Chem. Int. Ed200746, 5925–5928. (Inside Cover Page & referred in Wikipedia of water clusterhttp://en.wikipedia.org/wiki/Water_cluster).

  39. H. S. Sahoo, D. K. Chand, S. Mahalakshmi, M. H. Mir and R. Raghunathan, “Manifestation of diamagnetic chemical shifts of proton NMR signals by an anisotropic shielding effect of nitrate anions,” Tetrahedron lett200748, 761–765.

Awards

  1. Outstanding Scientist Award, VIRA 2018, Venus International Foundation
  2. Young Scientist Award, VIRA 2017, Venus International Foundation
  3. The Best Research Publication Award 2010, Department of Chemistry, National University of Singapore, Singapore
  4. AsCA Travel Award, Beijing, China, 2009 by Asian Crystallographic Association.
  5. The Best Graduate Researcher Award, 2008 in the Department of Chemistry, Faculty of Science, National University of Singapore, Singapore.

Ph.D. Thesis Guidance

PhD Degree Awarded

1. Dr. Faruk Ahmed

Ongoing PhD Scholars

1. Mr. Akhtaruzzaman

2. Mr. Basudeb Dutta (http://scholar.google.co.in/citations?user=1vA0tasAAAAJ&hl=en)

3. Mr. Sakhiul Islam (http://scholar.google.co.in/citations?user=TLoVT7YAAAAJ&hl=en)

4. Ms. Sanobar Naaz

Post-Doctoral Fellow 

1. Dr. Samim Khan (CSIR Research Associate)

Research Fellow

1. Mr. Sambhunath Bera (CSIR JRF)

MASTER Thesis Guidance

2014

Sk. Sirajul Islam

2015

Sabia Khatun

2016

Shahnaz Begum

Asia Parvin

Sarifun Khatun

2017

Jainab Khatun

Sanobar Naaz

Sanaul Islam

2018

Farha Yasmin

Najni Sultana

2019

Rukhsana Parvin

Project Works

Sponsored Projects

Principal Investigator of DST, SERB Project of worth Rs. 24.96 Lakhs (Grant No. SB/FT/CS-185/2012 Dated 30/07/2014)

Seminar/Conference/Workshop

Selected Conference Attended

  1. Poster Presentation: M. H. Mir, "Halogen•••Halogen Interactions in 2D Coordination Polymers Impact the Sorption Behavior" 2017 24th Congress - International Union of Crystallograph (IUCr 2017), August 2017, Hyderabad, India.
  2. Poster Presentation: M. H. Mir, G. K. Tan, L. L. Koh and J. J. Vittal, “Single-crystal to single-crystal photochemical structural transformations of interpenetrated 3D MOFs,” 2nd NUS-SNU Joint Symposium, March 2010, National University of Singapore, Singapore.
  3. Oral Presentation: M. H. Mir and J. J. Vittal, “Template Trapping of Elusive Cyclic Water Heptamers and Acyclic Water Helicate, (H2O)7Hosted by the Diamondoid Metal-Organic Frameworks”, 6th Singapore International Chemical Conference (SICC-6), December 2009, Singapore.
  4. Poster Presentation: M. H. Mir and J. J. Vittal, “New Water Clusters Hosted by Diamondoid MOFs,” The Joint Conference of the Asian Crystallographic Association and Chinese Crystallographic Society (AsCA’09), October 2009, Beijing, China.
  5. Invited Talk: M. H. Mir, S. Kitagawa and J. J. Vittal, “Two- and three-fold interpenetrated metal-organic frameworks from one-pot crystallization,” 4th Mathematics and Physical Science Graduate Conference (MPSGC), December 2008, National University of Singapore, Singapore.
  6. Invited Talk: M. H. Mir and J. J. Vittal, “Cyclic water heptamers, (H2O)­7­ inside MOFs,” 9th Frontier Science Symposium, October - 2008, National University of Singapore, Singapore.
  7. Participation: International Center for Materials Research (ICMR) Summer School on Periodic Structures and Crystal Chemistry, August-2008 at the University of California, Santa Barbara, USA.



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